Carbon nanotube “solar funnel” for smaller, more efficient solar cells
The size and efficiency of current photovoltaic (PV) cells means most people would probably have to cover large areas of their rooftops with such cells to even come close to meeting all their electricity needs. Using carbon nanotubes, MIT chemical engineers have now found a way to concentrate solar energy 100 times more than a regular PV cell. Such nanotubes could form antennas that capture and focus light energy, potentially allowing much smaller and more powerful solar arrays.
Solar panels generate electricity by converting photons (packets of light energy) into an electric current. The nanotube antenna created by an MIT research team led by Michael Strano, boosts the number of photons that can be captured and transforms the light into energy that can be funneled into a solar cell.
“Instead of having your whole roof be a photovoltaic cell, you could have little spots that were tiny photovoltaic cells, with antennas that would drive photons into them,” says Strano.
The new antennas might also be useful for any other application that requires light to be concentrated, such as night-vision goggles or telescopes.
Two layers of nanotubes
The antenna consists of a fibrous rope about 10 micrometers (millionths of a meter) long and four micrometers thick, containing about 30 million carbon nanotubes. Strano’s team built, for the first time, a fiber made of two layers of nanotubes with different electrical properties – specifically, different bandgaps.In any material, electrons can exist at different energy levels. When a photon strikes the surface, it excites an electron to a higher energy level, which is specific to the material. The interaction between the energized electron and the hole it leaves behind is called an exciton, and the difference in energy levels between the hole and the electron is known as the bandgap.
The inner layer of the antenna contains nanotubes with a small bandgap, and nanotubes in the outer layer have a higher bandgap. That’s important because excitons like to flow from high to low energy. In this case, that means the excitons in the outer layer flow to the inner layer, where they can exist in a lower (but still excited) energy state.
Therefore, when light energy strikes the material, all of the excitons flow to the center of the fiber, where they are concentrated. Strano and his team have not yet built a photovoltaic device using the antenna, but they plan to. In such a device, the antenna would concentrate photons before the photovoltaic cell converts them to an electrical current. This could be done by constructing the antenna around a core of semiconducting material.
The interface between the semiconductor and the nanotubes would separate the electron from the hole, with electrons being collected at one electrode touching the inner semiconductor, and holes collected at an electrode touching the nanotubes. This system would then generate electric current. The efficiency of such a solar cell would depend on the materials used for the electrode, according to the researchers.
Strano’s team is the first to construct nanotube fibers in which they can control the properties of different layers, an achievement made possible by recent advances in separating nanotubes with different properties.
Nanotube costs dropping
While the cost of carbon nanotubes was once prohibitive, it has been coming down in recent years as chemical companies build up their manufacturing capacity. “At some point in the near future, carbon nanotubes will likely be sold for pennies per pound, as polymers are sold,” says Strano. “With this cost, the addition to a solar cell might be negligible compared to the fabrication and raw material cost of the cell itself, just as coatings and polymer components are small parts of the cost of a photovoltaic cell.”Strano’s team is now working on ways to minimize the energy lost as excitons flow through the fiber, and on ways to generate more than one exciton per photon. Currently, the nanotube bundles lose about 13 percent of the energy they absorb, but the team is working on new antennas that would lose only one percent.
The MIT team describes their new carbon nanotube antenna, or “solar funnel,” in the Sept. 12 online edition of the journal Nature Materials.
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