Materials

Material that recycles sunlight could be next big leap for solar cells

Material that recycles sunligh...
An artist's depiction of what photon recycling looks like inside the crystalline structure of perovskite
An artist's depiction of what photon recycling looks like inside the crystalline structure of perovskite
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An artist's depiction of what photon recycling looks like inside the crystalline structure of perovskite
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An artist's depiction of what photon recycling looks like inside the crystalline structure of perovskite

If the rest of us have to recycle things like our milk cartons, junk mail and beer bottles, shouldn't solar cells have to abide by the same rules? That's part of the thinking in new research that's just come out of the University of Cambridge. Researchers there have discovered that a certain material can actually recycle photons from light, which could lead to solar cells that are orders of magnitude more efficient than anything currently in use.

The synthetic materials the researchers worked with are called hybrid lead halide perovskites, and they've already been in use as solar cells for some time. But they have a unique property that hasn't yet been exploited. It seems that after the material is struck by light, the light is turned into electrical energy, as with all solar cells. But with perovskite, after the electricity has been generated, part of that electrical charge reforms itself back into photons, or light. If solar cells could be developed that can grab and reuse these photons, they'd be able to pump out much more power from the same amount of light used by current cells.

"It's a massive demonstration of the quality of this material and opens the door to maximising the efficiency of solar cells," says Cambridge's Felix Deschler. "The fabrication methods that would be required to exploit this phenomenon are not complicated, and that should boost the efficiency of this technology significantly beyond what we have been able to achieve until now."

To verify that the lead halide perovskites do, in fact, use photon recycling, the researchers beamed a laser at a 500-nanometer-thick slice of the material. They then noticed that the light from this laser was re-emitted as a high-energy output elsewhere on the material.

"The high-energy component could not exist unless photons were being recycled," says lead author Luis Miguel Pazos Outón. He also pointed out that materials like silicon – commonly used in today's solar cells – don't have this ability to move energy through them and re-emit it as light.

Earlier this year, the US' National Renewable Energy Lab announced that a new record had been set for solar cells that were able to convert sunlight to electricity at the rate of 29.8 percent using a silicon-based cell. If the Cambridge research can be translated into a working solar cell, there's a good chance that record won't stand for long. Plus, with a recent advance that makes perovskite cells cheaper and more durable, silicon's days in the sun might soon be drawing to a close.

A paper describing the advance appears in the journal Science.

Source: University of Cambridge

8 comments
BartyLobethal
An "order of magnitude" is an increase (or decrease) of 10 times. This technology could only bring about an order-of-magnitude increase in efficiency for panels with efficiency in the single-digit percentage range. Nitpicking aside, this could still be a significant advance in conversion efficiency and is interesting as such.
splatman
@BartyLobethal, holding technical writers to impeccable standards of technical accuracy is not nitpicking. It's that kind of imprecision that leads to harmful misunderstandings and unrealistic expectations.
EcoLogical
Efficiency is only part of the equation, $/W is critical so efficiency provides benefit only if $/W goes down, ultimately reducing the $/kWh cost of energy.
Oun Kwon
Looks promising. But the word 'recycling' is not accurate for this. Howe about 'recapturing'? But that word would not sell well ;-)
Donald Vitez
Perhaps, the photons being emitted could be collected in a manner similar to a CO2 laser reflective resonator, so as to amplify the photon energy. Output coupler mirrors would then permit a portion of the bean to transmit exterior to the reflective resonator for use by the solar cell.
Douglas Bennett Rogers
A regular solar cell would emit waste heat in the form of IR photons. Most visible photons would convert to IR without producing an electron. Presumeably, these are mostly captured.
kriskret
Did you mention in the article above that inventor of this process is Polish scientist - young girl ?!!!
TomBateman
I'snt this phenomena the basis of fluorescence? When minerals ( crystalline solids) such as scheelite or calcite are irradiated with UV light a reradiation of visible light occurs