Graphene, the one-atom-thick material made up of a honeycomb lattice of carbon atoms, has produced yet another in a long list of experimental surprises. Its remarkable properties have already got researchers excited regarding its applications for faster computers, cheaper and more efficient batteries and vastly higher density mass data storage. Now researchers have reported the creation of pseudo-magnetic fields far stronger than the strongest magnetic fields ever sustained in a laboratory – just by putting the right kind of strain onto a patch of graphene. The breakthrough could have far reaching scientific applications.
“We have shown experimentally that when graphene is stretched to form nanobubbles on a platinum substrate, electrons behave as if they were subject to magnetic fields in excess of 300 tesla, even though no magnetic field has actually been applied,” says Michael Crommie, a faculty senior scientist in the Materials Sciences Division at the U.S. Department of Energy’s Lawrence Berkeley National Laboratory and a professor of physics at the University of California at Berkeley who headed a multi-institutional team of researchers who made the discovery. “This is a completely new physical effect that has no counterpart in any other condensed matter system.”
Crommie notes that “for over 100 years people have been sticking materials into magnetic fields to see how the electrons behave, but it’s impossible to sustain tremendously strong magnetic fields in a laboratory setting.” The current record is 85 tesla for a field that lasts only thousandths of a second. When stronger fields are created, the magnets blow themselves apart.
The ability to make electrons behave as if they were in magnetic fields of 300 tesla or more – just by stretching graphene – offers a new window on a source of important applications and fundamental scientific discoveries going back over a century. This is made possible by graphene’s electronic behavior, which is unlike any other material’s.
A carbon atom has four valence electrons; in graphene (and in graphite, a stack of graphene layers), three electrons bond in a plane with their neighbors to form a strong hexagonal pattern, like chicken-wire. The fourth electron sticks up out of the plane and is free to hop from one atom to the next. The latter pi-bond electrons act as if they have no mass at all, like photons. They can move at almost one percent of the speed of light.
Behavior predictedThe idea that a deformation of graphene might lead to the appearance of a pseudo-magnetic field first arose even before graphene sheets had been isolated, in the context of carbon nanotubes (which are simply rolled-up graphene). In early 2010, theorist Francisco Guinea of the Institute of Materials Science of Madrid and his colleagues developed these ideas and predicted that if graphene could be stretched along its three main crystallographic directions, it would effectively act as though it were placed in a uniform magnetic field. This is because strain changes the bond lengths between atoms and affects the way electrons move between them. The pseudo-magnetic field would reveal itself through its effects on electron orbits.
Prediction confirmedThe theory was confirmed when Crommie’s research group had been using a scanning tunneling microscope to study graphene monolayers grown on a platinum substrate. A scanning tunneling microscope works by using a sharp needle probe that skims along the surface of a material to measure minute changes in electrical current, revealing the density of electron states at each point in the scan while building an image of the surface.
“It showed nanobubbles, little pyramid-like protrusions, in a patch of graphene on the platinum surface,” Crommie says, “and associated with the graphene nanobubbles there were distinct peaks in the density of electron states.”
Close examination of the triangular bubbles revealed that their chicken-wire lattice had been stretched precisely along the three axes needed to induce the strain orientation that Guinea and his coworkers had predicted would give rise to pseudo-magnetic fields. The greater the curvature of the bubbles, the greater the strain, and the greater the strength of the pseudo-magnetic field. In some cases the increased density of electron states revealed by scanning tunneling spectroscopy indicated giant pseudo-magnetic fields of 300 tesla or more.
“Getting the right strain resulted from a combination of factors,” Crommie says. “To grow graphene on the platinum we had exposed the platinum to ethylene” – a simple compound of carbon and hydrogen – “and at high temperature the carbon atoms formed a sheet of graphene whose orientation was determined by the platinum’s lattice structure.”
To get the highest resolution from the scanning tunneling microscope, the system was then cooled to a few degrees above absolute zero. Both the graphene and the platinum contracted – but the platinum shrank more, with the result that excess graphene pushed up into bubbles, measuring four to 10 nanometers (billionths of a meter) across and from a third to more than two nanometers high.
Implications“Controlling where electrons live and how they move is an essential feature of all electronic devices,” says Crommie. “New types of control allow us to create new devices, and so our demonstration of strain engineering in graphene provides an entirely new way for mechanically controlling electronic structure in graphene. The effect is so strong that we could do it at room temperature.”
The opportunities for basic science with strain engineering are also huge. For example, in strong pseudo-magnetic fields electrons orbit in tight circles that bump up against one another, potentially leading to novel electron-electron interactions. Says Crommie, “this is the kind of physics that physicists love to explore.”
A paper detailing the discovery, “Strain-induced pseudo-magnetic fields greater than 300 tesla in graphene nanobubbles,” appears in the July 30 issue of Science.