Acid coating converts regular electrolyzers to split seawater
Green hydrogen is going to demand a lot of water for electrolysis – nine liters of pure water for every kilogram of hydrogen. Researchers say they've found a simple way to use seawater in standard electrolyzers, and that's big news for clean energy.
An international team from the University of Adelaide, Australia, Tianjin and Nankai Universities in China and Kent State University in the US has published new research claiming that a simple, cheap acid layer over the catalyst in an electrolyzer allows it to split seawater with "nearly 100 per cent efficiency," without any pre-treatment other than filtering.
A typical electrolyzer catalyst, says the team, might be made from cobalt oxide, with chromium oxide on its surface. Seawater would generally ruin these catalysts via severe erosion due to chlorine ions, or gunk them up with insoluble precipitations of magnesium and calcium, which build up and block the electrodes.
But the addition of a Lewis acid layer on the catalyst, it seems, was able to capture enough negatively charged hydroxyl anions from the seawater to generate a powerfully alkaline environment with a pH of 14 around the catalyst, stopping both chloride attacks on the catalyst and the formation of precipitates on the electrodes.
“We have split natural seawater into oxygen and hydrogen with nearly 100 per cent efficiency, to produce green hydrogen by electrolysis, using a non-precious and cheap catalyst in a commercial electrolyzer,” said Professor Shizhang Qiao.
"The performance of a commercial electrolyzer with our catalysts running in seawater is close to the performance of platinum/iridium catalysts running in a feedstock of highly purified deionized water," added Associate Professor Yau Zheng.
Two things seem clear looking at the decades ahead: there's going to be a lot of demand for green hydrogen, and the water shortages that are projected to impact two-thirds of the world's population by 2025 are going to get worse.
But if green hydrogen can be made in bulk using seawater, then anywhere it's used, either in a fuel cell or in a combustion process, it'll end up being combined with oxygen and released back into the environment as fresh water – a desalination process with a clean energy bonus, if you will.
The team says it's working to scale up its system for commercial-scale electrolyzers, and looking for industrial partners to take it into production.
The paper is available in the journal Nature Energy.
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My view is that the projection is off the mark so much because planners are not considering Hydrogen enough. My prediction is that sometime before 2030, when enough s**t hits the fan, there will be a mad scramble for the only technically feasible solution: hydrogen.
By my calculations, a 100% hydrogen economy for the US (not considering nonfuel petrochemicals) will require about 3.8 gallons of water per citizen per day for all the electrolysis required. We get back about 2.4 gallons per citizen per day from the Utility and Transportation fuel cells. That's a net of about 17 billion gallons a year required.