Materials

Teflon-like desalination membrane purifies water fast and friction-free

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A new type of water desalination membrane uses tiny rings of fluorine to repel salt
A new type of water desalination membrane uses tiny rings of fluorine to repel salt
Fluorine rings measuring between 0.9 and 1.9 nanometers wide allow water to pass through with little friction, while the negative charge repels ions in salt
2022 Itoh et al.

Engineers at the University of Tokyo have developed a new type of desalination membrane that they claim is faster, and requires less pressure and energy than existing tech. The new membrane is made up of a series of nanoscale tubes lined with a Teflon-inspired material that repels salts while allowing water to flow through with little friction.

Many regions around the world face a scarcity of clean drinking water, and the problem is only going to worsen with a changing climate. Desalinating brackish water or seawater is vital, and there’s no shortage of creative devices in the works, either using heat to evaporate and recondense water or membranes to filter salt and impurities out.

The new system is a variation on the latter, but has a few advantages over others of its kind. The key ingredient is fluorine, a hydrophobic material that gives Teflon its famous non-stick properties. It isn’t just used for cookware, however – fluorine-based coatings are often used for pipes to keep water flowing through smoothly.

The new membrane contains stacks of nanoscale rings made of fluorine, embedded in a lipid layer that’s impermeable to water. Not only does the fluorine help the water slip through the rings with very little friction, but its negative charge conveniently repels salts, preventing them from passing through.

The team tested the technique by making membranes with fluorine nanorings of between 0.9 and 1.9 nanometers wide, then flowed saltwater through them. They then measured the amount of chlorine ions – a major component of salt – on either side of the membrane. And sure enough, the fluorine rings filtered the water faster and more effectively, using less pressure and energy than other desalination methods.

Fluorine rings measuring between 0.9 and 1.9 nanometers wide allow water to pass through with little friction, while the negative charge repels ions in salt
2022 Itoh et al.

“It was very exciting to see the results firsthand,” said Yoshimitsu Itoh, lead author of the study. "The smaller of our test channels perfectly rejected incoming salt molecules, and the larger channels too were still an improvement over other desalination techniques and even cutting-edge carbon nanotube filters. The real surprise to me was how fast the process occurred. Our sample worked around several thousand times faster than typical industrial devices, and around 2,400 times faster than experimental carbon nanotube-based desalination devices.”

As an aside: the word “Teflon” may immediately ring alarm bells for health concerns in some people, but fluorine isn’t the chemical of concern in that regard.

The team plans to conduct further research into lowering the amount of energy required to make the fluorine nanoring membranes, with an eye towards scaling up the membranes, starting with a 1-m-wide (3.3-ft) test membrane in the next few years.

The research was published in the journal Science.

Source: University of Tokyo

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6 comments
Capt_Ahab84
I wonder if this membrane is small enough to also filter out pathogens and, if so, is it susceptible to biofouling?
paul314
Do these fluorinated compounds break down readily when their use time is over? (And not leach into the water they're purifying?)
Username
Where does the salt go? Does the membrane require to be backwashed?
Nelson Hyde Chick
I wonder what will be the unanticipated consequences of this "Teflon" like material? Teflon gave us stick free cookware and later we learned it heightened are risk of cancer: https://www.healthline.com/health/teflon-cancer
Expanded Viewpoint
"Salt molecules"??? Just who are these chemists? Where did they get their education in chemistry? There is no such thing as a molecule of ANY kind of a salt, unless it is a super fine powdered form of a salt crystal. A salt is the result of reacting a metal with a non-metal, and is a crystal that dissolves in water. When you dissolve any salt, such as common table salt (NaCl), in the water you will have Sodium atoms in their ionic form and Chlorine atoms in their ionic form. When the water is gone, the salt crystals will reform again from those ionized atoms, unless you extract either one or both of them from the water. There are compound salts as well.
Eggster
I'm curious about the amount of pressure required for this to work. Could this be made to work under the pressure resulting from the weight of the water alone?