Caltech reactor could convert CO2 into breathable oxygen for space trips

Caltech reactor could convert ...
Konstantinos Giapis, with the reactor that converts carbon dioxide into molecular oxygen
Konstantinos Giapis, with the reactor that converts carbon dioxide into molecular oxygen
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Konstantinos Giapis, with the reactor that converts carbon dioxide into molecular oxygen
Konstantinos Giapis, with the reactor that converts carbon dioxide into molecular oxygen
Tom Miller, co-author of the study
Tom Miller, co-author of the study

Although oxygen is common throughout the cosmos, most of it isn't in the form that we as humans need to breathe – molecular oxygen, or O2. Now, researchers at Caltech claim to have created a reactor that can turn carbon dioxide into molecular oxygen, which could help us fight climate change here on Earth or generate oxygen for life in space.

Oxygen is one of the biggest hurdles to human space exploration. Earth is the only place we know of that has the vital gas in breathable quantities, and taking it with us is expensive and unsustainable. On the International Space Station, the crew breathes easy thanks to electrolysis – where water is zapped to split it into its constituent hydrogen and oxygen gases – along with a pressurized storage tank for backup. There's talk of terraforming Mars to be more Earth-like, but that's a huge undertaking that isn't remotely possible with today's technology.

So the researchers on the new study set out to find another way to produce oxygen. They ended up creating a reactor that, in a sense, sounds very simple – take CO2, then strip out the C. The team found that if you shoot carbon dioxide at an inert surface like gold foil, the molecule can be split to form molecular oxygen and atomic carbon.

The team says the reactor works in a similar fashion to a particle accelerator. The CO2 molecules are first ionized and then accelerated using an electric field, before being slammed into the gold surface. In its current form the yield is pretty low – only creating about one or two oxygen molecules for every 100 CO2 molecules fired – but it's an intriguing proof of concept that could be scaled up in the future.

In fact, the researchers say the reaction occurs in nature. The concept began as an attempt to explain the unexpected discovery of molecular oxygen on comets. After the Rosetta spacecraft detected the gas streaming out of Comet 67P, it was originally believed that the oxygen must have been locked away in the rock for billions of years.

But in 2017 the Caltech team proposed another possible explanation: that the oxygen was being created by other compounds slamming into the comet at high speeds. After molecules of water or carbon dioxide are emitted from the comet, the solar winds can accelerate them and slam them back into the comet. That in turn could create molecular oxygen, and served as the inspiration for the Caltech reactor.

Tom Miller, co-author of the study
Tom Miller, co-author of the study

In future, the reactor could potentially be put to work producing oxygen for astronauts traveling to the Moon, Mars or beyond. Or, back here on Earth, it might be useful for removing CO2 from the atmosphere and converting it into oxygen, to help combat climate change. Of course, there's still plenty of work left to do to get it to that stage.

"Is it a final device? No," says Konstantinos Giapis, lead author of the study. "Is it a device that can solve the problem with Mars? No. But it is a device that can do something that is very hard. We are doing some crazy things with this reactor."

The research was published in the journal Nature Communications.

Source: Caltech

F. Tuijn
This sounds like an good way to produce a lot of waste heat even were it to produce 80 oxygen molecules from every 100 carbon dioxide molecules.
Currently, oxygen for astronauts is generated using water or using chemicals & both are one-time-use!
Meaning, keep carrying tons of water/chemicals to orbit, to be able to keep making oxygen!
So, any device that can turn CO2 (in the air) back to O2, using only electricity, is extremely valuable/practical tech for space!
There's another device to turn CO2 into oxygen or 02 it's called a plant and then you get to eat it.
Converting CO2 into C and O2 is Victorian science. Another group ''reinventing the wheel!''
Phil McKrack
'Only creating about one or two oxygen molecules for every 100 CO2 molecules fired'.
With more funding and research into this technology, say a year from now, it might be creating 20 oxygen molecules for every 100 CO2 molecules fired. Give it another year and it might be 50 molecules, then 100, 500, 1000. Just because it's not reasonable right now doesn't mean it always will be. Imagine dropping one of these on Mars and say in 5-10 years time when we finally set foot on the red planet it has oxygen.
Fascinating to read this - especially in April 2021, when Covid-19 rages across the world and countries like mine - India - are struggling to ramp up production of medical-grade oxygen.
Strength to researchers such as these who refuse to follow beaten paths, who dare to explore, who shrug away the mockery of the masses and just do what they love doing...for the greater good.